Visible light-promoted metal-free aerobic photooxidation of xanthenes, thioxanthenes and dihydroacridines in deep eutectic solvents

  1. Burlingham, Sarah-Jayne
  2. Torregrosa-Chinillach, Alejandro
  3. Alonso, Diego A. 1
  4. Chinchilla, Rafael 1
  1. 1 Universitat d'Alacant
    info

    Universitat d'Alacant

    Alicante, España

    ROR https://ror.org/05t8bcz72

Revista:
Tetrahedron Green Chem

ISSN: 2773-2231

Año de publicación: 2023

Volumen: 2

Páginas: 100030

Tipo: Artículo

DOI: 10.1016/J.TGCHEM.2023.100030 GOOGLE SCHOLAR lock_openAcceso abierto editor

Otras publicaciones en: Tetrahedron Green Chem

Resumen

Benzylic systems such as 9H-xanthenes, 9H-thioxanthenes and 9,10-dihydroacridines can be easily oxidized to the corresponding xanthones, thioxanthones or acridones, respectively, in deep eutectic solvents by a visible blue light-promoted photooxidation procedure carried out using ambient air as oxidant in the presence of riboflavin tetraacetate as a metal-free photocatalyst. The obtained yields are high or almost quantitative, and the reaction media can be recovered and reused. The environmental friendliness of the protocol is demonstrated based on several green metrics.

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