Tailoring the Surface Chemistry of Zeolite Templated Carbon by
- Berenguer Betrián, Raul
- Morallón, Emilia
- Cazorla Amorós, Diego
- Nishihara, H.
- Itoi, H.
- Ishii, T.
- Kyotani, T.
ISSN: 2172-6094
Year of publication: 2013
Issue: 28
Pages: 10-14
Type: Article
More publications in: Boletín del Grupo Español del Carbón
Abstract
One option to optimize carbon materials for supercapacitor applications is the generation of surface functional groups that contribute to the pseudocapacitance without losing the designed physical properties. This requires suitable functionalization techniques able to selectively introduce a given amount of electroactive oxygen groups. In this work, the influence of the chemical and electrochemical oxidation methods, on the chemical and physical properties of a zeolite templated carbon (ZTC), as a model carbon material, have been studied and compared. Although both oxidation methods generally produce a loss of the original ZTC physical properties with increasing amount of oxidation, the electrochemical method shows much better controllability and, unlike chemical treatments, enables the generation of a large number of oxygen groups (O = 11000- 3300 ìmol/g), with a higher proportion of active functionalities, while retaining a high surface area (ranging between 1900-3500 m2/g), a high microporosity and an ordered 3-D structure.